I've tried many different brownie recipes and most of mine bake to a cake-like consistency. The brownie holy grail for me is crusty top chewy brownies. What can I add/remove/do that will make my brownies chewier?
One of the most important factors in achieving a fudgy, chewy brownie is cooking time. Essentially you should be slightly undercooking the brownies so they don't dry out in the middle.
Use the cooking times given in recipes as a guide only, because each oven will vary. 5-10 minutes before they 'should' be ready, start testing the centre of the brownies with a toothpick or cake tester: unlike a cake, you want a good amount of sticky crumbs on the skewer (but very little liquid batter). Remember that the cooking process will continue even once the brownies are out of the oven.
Another factor that contributes to chewiness is the sugars you use: adding some sticky, dense, dark sugar will help create a fudgy brownie. The brownie recipe I use, which is pretty damn good, uses 1.5 cups of granulated sugar and .5 cup of packed dark brown sugar.
America's Test Kitchen (AKA Cook's Illustrated) took on exactly this issue. They were looking for both that chewy texture and that shiny, crusty, crackly top. Good boxed brownie mixes achieve those qualities, but lack the intense chocolaty taste of homemade. They tried different mixing methods. They tried melting the butter, creaming the butter, and different sweeteners. They tried a pizza stone and they tried an ice bath. Nothing worked until they went to their science editor.
It was the science editor who suggested that their problem was the ratio of saturated vs unsaturated fat. Sure enough, the good boxed brands had almost the reverse ratio of saturated vs unsaturated fat of the recipes they had been working with. So they upped their vegetable oil, and reduced the amount of butter. They also added two egg yolks for their emulsifying ability. I can say from experience that the vegetable oil wants to separate from the rest of the batter until those yolks are added. If you instinctively jump to the idea that more egg will defeat the purpose and make the brownies more cakey, it's the white that does that, not the yolk.
The classic recipes that they had been working with had 36% unsaturated fat to 64% saturated. Their Chewy Brownie recipe has 71% unsaturated to 29% saturated.
As far as the shiny, crackly top, they found that plain white, granulated cane sugar was the best sweetener for achieving that.
Certainly, overcooking even these brownies will destroy that chewy texture. You want to remove them from the oven while they're still underdone. Carry-over cooking will complete the baking.
The recipe can be found here: Chewy Brownies but it's paywalled. If you don't have a subscription, they do offer a 14 day free trail. You can pretty well suck the marrow out of the site in 14 days, and they will not charge your card if you cancel in that 14 day window.
Here's a picture of mine. Of course, you can't tell from this how chewy they are (very), but you can see the shiny, crackly top.
the secret is corn syrup (20-30% of sugar) and undermixing/underbaking
Use REALLY high quality Dutch Process Cocoa. Contrary to what is often seen, oil is not the answer to chewy brownies. Good cocoa, and bake them in a 9x9 pan, not 9x13 (think surface area to volume here). I do not recommend undercooking, in my experience the texture is "off" in undercooked brownies.
Watch them carefully. When the toothpick test is good (it comes out clean), get them out of the oven right away.