The difference between gluten and gliadin is the one already explained in your question: Gliadin is a precursor to gluten. You could say that gliadin is to gluten what grains are to porridge. Gluten is the result of glutenin reacting with gliadin in the presence of water, just like porridge is the result of grains "reacting" with milk in the presence of heat.
I don't understand why you are asking for separating them. It would be hard to do, and will achieve no good purpose.
First, I don't know if there is a way to extract the gliadin from wheat. There are industrial processes for extracting "gluten" out of wheat, but I don't know if they produce a mixture of glutenin and gliadin (which could be further purified) or if they already cause the glutenin and gliadin to bind a gluten. But note that the remaining flour will not be gluten-free, as these methods cannot extract every last molecule of glutenin and gliadin. So you cannot remove the glutenin from flour and stay with gliadin-containing flour.
Second, assuming that you can extract the gliadin, you can add it to some gluten free flour like cornflour. But there is absolutely no reason doing so. The definition you cited only says that gliadin is "essential" for rising, but not that it alone produces rising. It is the gluten itself that produces rising, and the gliadin is essential only because without it, there would be no gluten. Gliadin alone does not have any benefits.
Third, if you add gliadin to a gluten free flour, you will not have removed any of the problems inherent in using gluten. People who are allergic to gluten will still be allergic to the gliadin.
To sum it up, gliadin is a structural part of gluten, and if you can find a method to extract it without the glutenin, you will experience no benefits of baking with it, or prevent any undesired side effects like triggering allergies or celiac.