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I’d like to make truffles with brownie crumbs and ganache and freeze the balls to be rolled in cocoa powder or nuts when thawed. Has anyone done this?

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I have not made explicitly what you're asking for, but I regularly freeze ganache, with no ill effects. Just be careful when you thaw them. Don't leave them out 'naked' in room temperature air, or you will get condensation on them.

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