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Why should I cook the flour first with butter, instead of just combining all the ingredients until I get the desired consistency when making a bechamel sauce?

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    It's not the reason that it's been done for centuries, but these days raw flour is a known vector for food poisoning in the US. (so those 'safe to eat raw cookie dough' recipes you see online aren't actually safe just because they left out eggs). So at least in the US, you really want to cook your flour
    – Joe
    Commented Jul 15, 2019 at 14:51
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    The raw cookie dough recipes are safer if they include a step for pasteurizing the flour. Commented Jul 16, 2019 at 1:32
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    @JamesMcLeod yeah i know the flour its baked to remove rawness... Commented Jul 16, 2019 at 5:22

4 Answers 4

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This link explains the science behind what is known as "the mother sauce", béchamel. Essentially, the steps of first creating a roux, then adding cold milk, are about manipulating the glucose chains in the flour. Done correctly, the sauce is smooth and flavorful. Done incorrectly and you have a grainy mixture that tastes of raw flour.

@David Richerby's comment below prompted me to investigate further. So, I turned to Harold McGee's classic, On Food and Cooking. He writes, on page 617, that:

in addition to coating flour particles with fat, making them easier to disperse in a hot liquid, roux making has three other useful effects on flour....it cooks out the raw cereal flavor, and develops a round, toasty flavor...second, the color itself...and third, heat causes some of the starch chains to split, and then to form new bonds with each other.

He goes on to explain the importance of this step, but it generally achieves the desired texture and means the sauce is less likely to congeal on the plate.

From Wikipedia's page on starch:

Starch or amylum is a polymeric carbohydrate consisting of a large number of glucose units joined by glycosidic bonds.

...and, yes, this correlates with gelatinization.

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    Hmm. I'm not at all convinced by the explanation in the article you link: it seems to claim that it's about hydrolysing starch molecules into shorter chains whereas I think the actual science is starch gelatinization. I'm also disinclined to trust somebody who thinks that adding a couple of tablespoons of cornstarch slurry will catastrophically dilute a gravy. Commented Jul 15, 2019 at 15:46
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Flour has to be cooked in any kind of fat, butter or oil to remove the rawness of the flour. If you don't roast and put all the ingredients straightway and cook for longer time, it would still work, but in that case you'll have to cook for bit longer and reduce the ratio of flour. Otherwise the sauce will thicken up and it would taste raw as it wasn't cooked.

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It's very difficult to just mix flour with a liquid. It will set to the bottom of the sauce pan and clump when heated, unless you stir constantly.

This is why you make a roux first, combining the flour with some kind of fat. You could just mix flour with cold butter until well combined and add it to hot liquid such as milk and it would thicken just fine (I use this technique when I want to thicken a sauce when it's almost done and i find it a bit too runny.)

However, by first heating the oil and flour you take the raw edge of the flour as well, or even give it a nice toasted flavor profile, which is desired in many cases.

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It is important that after "frying" the flour and fat you turn off the heat and add the first liquid (water, stock, milk) slowly while stirring. Later you can add liquid more quickly and turn the heat back on. In common with the other answers: this avoids clumps.

I sometimes make a roux from peanut butter, flour, spices, milk, water. Yummie. Without the extra flour there would be too much peanut oil. Mixing hot oil / fat / butter with the flour first gives you an idea of the right proportions, it has to form an almost-dry ball.

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    It's not important at all. You can make bechamel by cooking the roux and then dumping all the milk in at once with the heat still on. As long as you whisk it, you won't get any lumps. I don't wonder that you have problems getting a lump-free sauce if your roux is "an almost-dry ball" -- that doesn't sound like anything I'd recognize as a roux. Commented Jul 16, 2019 at 10:31
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    Also, I don't understand what you mean by "Without the extra flour, there would be too much peanut oil." The flour is an integral part of the roux: it's not there to mop up oil but, rather, it's the starch from the flour that thickens the sauce. As far as I'm aware, the oil doesn't really do anything except allow you to cook the starches. Commented Jul 16, 2019 at 10:32

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